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Green Metathesis Chemistry: Great Challenges in Synthesis, Catalysis and Nanotechnology
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SYSNO ASEP 0341541 Document Type M - Monograph Chapter R&D Document Type Monograph Chapter Title [RuCl2(p-cymene)]2 immobilized on mesoporous molecular sieves SBA-15 as catalyst for ROMP of norbornene Author(s) Bek, David (UFCH-W)
Balcar, Hynek (UFCH-W) RID, ORCID
Sedláček, J. (CZ)Source Title Green Metathesis Chemistry: Great Challenges in Synthesis, Catalysis and Nanotechnology. - Dordrecht : Springer, 2010 / Dragutan V. ; Demonceau A. ; Dragutan I. ; Finkelshtein E. S. - ISBN 978-90-481-3432-8 Pages s. 391-400 Number of pages 10 s. Number of pages 425 Language eng - English Country NL - Netherlands Keywords metathesis ; ROMP ; norbornene Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects IAA400400805 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) GD203/08/H032 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000280129600025 EID SCOPUS 84867024726 Annotation A new heterogeneous catalyst for ring opening metathesis polymerization (ROMP) has been prepared by immobilization of [RuCl2(p-cymene)]2 on siliceous mesoporous molecular sieves SBA-15. Activity of the catalyst was tested in ROMP of norbornene. Filtration test proved that the catalytic activity as bound to the solid phase. Catalyst could be easily separated from reaction mixture in contrast to the corresponding homogeneous system and therefore polymer with reduced amounts of catalyst residues was obtained. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2011
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