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Synthesis of thermally responsive cylindrical molecular brushes via a combination of nitroxide-mediated radical polymerization and “grafting onto” strategy
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SYSNO ASEP 0341122 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Synthesis of thermally responsive cylindrical molecular brushes via a combination of nitroxide-mediated radical polymerization and “grafting onto” strategy Author(s) Gromadzki, Daniel (UMCH-V) RID
Jigounov, Alexander (UMCH-V) RID, ORCID
Štěpánek, Petr (UMCH-V) RID, ORCID
Makuška, R. (LT)Source Title European Polymer Journal. - : Elsevier - ISSN 0014-3057
Roč. 46, č. 4 (2010), s. 804-813Number of pages 10 s. Language eng - English Country GB - United Kingdom Keywords nitroxide-mediated radical polymerization ; grafting onto ; thermally responsive cylindrical brushes Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects GA202/09/2078 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000276790500020 DOI 10.1016/j.eurpolymj.2009.12.015 Annotation It was demonstrated that the combination of nitroxide-mediated radical polymerization and "grafting onto" Williamson etherification reaction can be successfully used for the synthesis of loosely grafted amphiphilic molecular brushes. The amphiphilic behavior of molecular brush PS-MPEG was validated by 1H NMR spectroscopy in solvents selective for the respective hydrophobic and hydrophilic segments. Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2010
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