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Luminescent impurity ion probe and low temperature phase of SrTiO.sub.3./sub. nanoparticles
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SYSNO ASEP 0336486 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Luminescent impurity ion probe and low temperature phase of SrTiO3 nanoparticles Title Luminiscenční sonda iontů příměsi a nízkoteplotní fáze nanočástic SrTiO3. Author(s) Potůček, Zdeněk (FZU-D) RID, ORCID
Trepakov, Vladimír (FZU-D) RID
Makarova, Marina (FZU-D) RID, ORCID
Sazama, Petr (UFCH-W) RID, ORCID
Badalyan, A. G. (RU)
Dejneka, Alexandr (FZU-D) RID, ORCID
Jastrabík, Lubomír (FZU-D) RID, ORCIDNumber of authors 7 Source Title Materials Science and Technology - ISSN 0267-0836
Roč. 25, č. 11 (2009), s. 1334-1340Number of pages 7 s. Language eng - English Country GB - United Kingdom Keywords strontium titanate ; nanocrystals ; impurity ions ; optical absorption ; zero-phonon line Subject RIV BM - Solid Matter Physics ; Magnetism R&D Projects GA202/08/1009 GA ČR - Czech Science Foundation (CSF) KJB100100703 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) KAN301370701 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) 1M06002 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) CEZ AV0Z10100522 - FZU-D (2005-2011) AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000272049300009 DOI 10.1179/026708309X12474766656416 Annotation Photoluminescence of Cr3+ impurity ions was studied on nanocrystalline SrTiO3:Cr(0.1%) powders with an average particle size between 13 and 100 nm. The position of the zero-phonon emission R-line of the octahedral Cr3+ centres shifted to higher energies with decreasing particle size. The temperature shift of the R-line position appeared for all powders nearly the same as the 'dielectric related' one in the bulk crystals, evidencing that SrTiO3 retains quantum paraelectric behaviour down to a particle size of about 10 nm. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2010
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