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Boron Atoms as Spin Carriers in Two- and Three-Dimensional Systems
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SYSNO ASEP 0335819 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Boron Atoms as Spin Carriers in Two- and Three-Dimensional Systems Title Atomy boru jako nosiče spinu ve dvou- a tří- rozměrných systémech Author(s) Kaim, W. (DE)
Hosmane, N. S. (US)
Záliš, Stanislav (UFCH-W) RID, ORCID
Maguire, J. A. (US)
Lipscomb, W. N. (US)Source Title Angewandte Chemie - International Edition. - : Wiley - ISSN 1433-7851
Roč. 48, č. 28 (2009), s. 5082-5091Number of pages 10 s. Language eng - English Country DE - Germany Keywords boron ; cluster compounds ; organoboranes ; radicals Subject RIV CG - Electrochemistry R&D Projects OC 139 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) KAN100400702 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000267809800004 DOI 10.1002/anie.200803493 Annotation Paramagnetic compounds with at least partially boron-centered electron spin can be constructed using either the prototypically electron-accepting boron atoms bridged by planar -conjugated organic systems, or by taking advantage of the three-dimensional delocalized bonding in oligonuclear borane, haloborane, or carborane clusters. The concept of mixed valency can thus be transferred from organic and transition-metal chemistry to main-group-element molecules, and density functional theory is capable of reproducing the variable spin distribution. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2010
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