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Thallium dynamics in contrasting light sandy soils-Soil vulnerability assessment to anthropogenic contamination
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SYSNO ASEP 0334609 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Thallium dynamics in contrasting light sandy soils-Soil vulnerability assessment to anthropogenic contamination Author(s) Vaněk, A. (CZ)
Chrastný, V. (CZ)
Komárek, M. (CZ)
Galušková, I. (CZ)
Drahota, Petr (GLU-S) SAI, RID, ORCID
Grygar, Tomáš (UACH-T)
Tejnecký, V. (CZ)
Drábek, O. (CZ)Source Title Journal of Hazardous Materials. - : Elsevier - ISSN 0304-3894
Roč. 173, 1/3 (2010), s. 717-723Number of pages 7 s. Publication form WWW - WWW Language eng - English Country NL - Netherlands Keywords thallium ; soil ; LMWOA ; retention ; mobility Subject RIV DF - Soil Science CEZ AV0Z30130516 - GLU-S (2005-2011) AV0Z40320502 - UACH-T (2005-2011) UT WOS 000273135600101 EID SCOPUS 71749111273 DOI 10.1016/j.jhazmat.2009.08.144 Annotation The influence of different soil conditions and the presence of LMWOA (Low Molecular Weight Organic Acids) on anthropogenic Tl dynamics were discussed in this study. A shift from the “labile” to the residual fraction during the ageing was identified, indicating Tl incorporation into stable phases (e.g., illite and/or amorphous silicates). The increased water-soluble Tl concentration (1.8 fold, in maximum) after the split application of LMWOA was observed in all soils; partial dissolution of relatively “insoluble” Tl-bearing phases (silicates and eventually oxides) in the presence of LMWOA is suggested. Manganese(III,IV) oxides, illite and amorphous silicates were evaluated as the dominant phases responsible for Tl retention in the soils. In carbonate-rich soils, Tl coprecipitation with the newly formed carbonates seems to be an important factor influencing Tl release. Therefore, we suggest data on CEC, pHZPC and soil mineralogy to be critical for assessment of Tl behavior in soils. Workplace Institute of Geology Contact Jana Popelková, popelkova@gli.cas.cz, Sabina Janíčková, Tel.: 233 087 272 Year of Publishing 2010
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