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Isotope-sensitive Degenerate [1.3]-Hydrogen Migration versus Competitive Enol-Keto Tautomerization
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SYSNO ASEP 0334353 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Isotope-sensitive Degenerate [1.3]-Hydrogen Migration versus Competitive Enol-Keto Tautomerization Author(s) Zhang, X. (DE)
Zummack, W. (DE)
Schröder, Detlef (UOCHB-X)
Weinhold, F. A. (US)
Schwarz, H. (DE)Number of authors 5 Source Title Chemistry - A European Journal. - : Wiley - ISSN 0947-6539
Roč. 15, č. 44 (2009), s. 11815-11819Number of pages 5 s. Language eng - English Country DE - Germany Keywords reaction mechanism ; hydrogen migration ; non-ergodic behavior ; keto-enol tautomerism ; isotope effects Subject RIV CF - Physical ; Theoretical Chemistry CEZ AV0Z40550506 - UOCHB-X (2005-2011) UT WOS 000272109100004 DOI 10.1002/chem.200902176 Annotation A careful re-investigation of the acetone cation-radical not only provides additional mechanistic insight, but reveals a degenerate 1,3-H migration as a completely novel facet. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434 Year of Publishing 2010
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