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XPS study of early stages of Al/Au interface formation
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SYSNO ASEP 0329507 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title XPS study of early stages of Al/Au interface formation Title XPS studium počátečních fází při tvorbě Al/Au mezifází Author(s) Polyak, Yaroslav (UFCH-W)
Bastl, Zdeněk (UFCH-W) RID, ORCIDSource Title Surface and Interface Analysis. - : Wiley - ISSN 0142-2421
Roč. 41, č. 10 (2009), s. 830-833Number of pages 4 s. Language eng - English Country GB - United Kingdom Keywords XPS ; Al/Au interface ; Au(4f) doublet ; liquid nitrogen temperature ; thermodynamic stability Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects KAN100400702 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) GA104/08/1501 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000270844900010 DOI 10.1002/sia.3109 Annotation The interface formation between Au polycrystalline substrate kept at temperature of liquid nitrogen and Al deposit and its evolution during sample thermal treatments have been investigated by means of XPS. The intermixing of the Al and Au atoms at the interface occurred readily already at temperature of liquid nitrogen and resulted in the appearance of well-resolved components on the high-binding-energy side of the Au(4f) spectra assignable to AlAu intermetallic phase. The sample annealing resulted in the growth of the amount of intermetallic compound formed at liquid nitrogen temperature. The formation of the initial AlAu phase at the Al/Au interface in our experimental conditions can be explained on the basis of its thermodynamic stability. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2010
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