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Annual Reports on NMR Spectroscopy
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SYSNO ASEP 0328700 Document Type M - Monograph Chapter R&D Document Type Monograph Chapter Title Applications of Silicon-Carbon Coupling Constants Title Užití kapling konstant křemík-uhlík Author(s) Blechta, Vratislav (UCHP-M) RID, ORCID, SAI Source Title Annual Reports on NMR Spectroscopy, 2 - Chapter. - Amsterdam : Elsevier, 2009 / Webb G.A. - ISBN 978-0-12-375058-7 Pages s. 97-264 Number of pages 168 s. Number of copy 10000 Number of pages 435 Language eng - English Country NL - Netherlands Keywords silicon-carbon coupling constants ; 29Si NMR ; 13C NMR Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects GA203/06/0738 GA ČR - Czech Science Foundation (CSF) IAA400720706 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40720504 - UCHP-M (2005-2011) Annotation Experimental methods used for detection of silicon-carbon coupling constants are summarized with emphasis to multiple-bond couplings. Values of silicon-carbon coupling constants are related to electronic structure parameters like electronegativity of substituents, s- character of silicon-carbon bond, s-electron densities and others. Extensive tables of silicon-carbon coupling constants are given in appendices. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2010
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