Number of the records: 1

Simple and Fast Synthesis of New Axially Chiral Bipyridine N,N’-Dioxides for Highly Enantioselective Allylation of Aldehydes

SYSNO ASEP	0327368
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Simple and Fast Synthesis of New Axially Chiral Bipyridine N,N’-Dioxides for Highly Enantioselective Allylation of Aldehydes
Author(s)	Kadlčíková, A. (CZ) Hrdina, R. (CZ) Valterová, Irena (UOCHB-X)_{RID, ORCID} Kotora, Martin (UOCHB-X)_{RID, ORCID}
Number of authors	4
Source Title	Advanced Synthesis & Catalysis. - : Wiley - ISSN 1615-4150 Roč. 351, č. 9 (2009), s. 1279-1283
Number of pages	5 s.
Language	eng - English
Country	DE - Germany
Keywords	asymmetric catalysis ; cobalt ; cyclotrimerization
Subject RIV	CC - Organic Chemistry
CEZ	AV0Z40550506 - UOCHB-X (2005-2011)
UT WOS	000267894000014
DOI	10.1002/adsc.200900224
Annotation	Unsymmetrically 3,3’-substituted axially chiral bis(tetrahydroisoquinoline) N,N’-dioxides exhibit unique catalytic activity in the asymmetric allylation of aromatic aldehydes (up to 96% ee). The product of the enantioselective allylation of benzaldehyde served as a building block for the preparation of an intermediate in the synthesis of diospongines.
Workplace	Institute of Organic Chemistry and Biochemistry
Contact	asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434
Year of Publishing	2010

Number of the records: 1