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Transformation of Vegetable Oils into Hydrocarbons over Mesoporous-Alumina-Supported CoMo Catalysts
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SYSNO ASEP 0326725 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Transformation of Vegetable Oils into Hydrocarbons over Mesoporous-Alumina-Supported CoMo Catalysts Author(s) Kubička, D. (CZ)
Šimáček, P. (CZ)
Žilková, Naděžda (UFCH-W) RID, ORCIDSource Title Topics in Catalysis. - : Springer - ISSN 1022-5528
Roč. 52, 1-2 (2009), s. 161-168Number of pages 8 s. Language eng - English Country NL - Netherlands Keywords organized mesoporous alumina ; CoMo catalysts ; hydrodeoxygenation Subject RIV CF - Physical ; Theoretical Chemistry CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000263428100016 DOI 10.1007/s11244-008-9145-5 Annotation Deoxygenation of triglycerides over organized-mesoporous-alumina-supported CoMo catalysts (CoMo/OMA) has been investigated in this work. CoMo/OMA catalysts exhibited higher activity for deoxygenation of triglycerides than CoMo supported on MCM-41 (silica) and ordinary alumina supports. Two main deoxygenation pathways were found: hydrodeoxygenation and hydrodecarboxylation. Their extent was affected by reaction temperature, pressure and the support used. Hydrodeoxygenation was the main reaction under the studied conditions. The extent of hydrodecarboxylation increased with increasing reaction temperature and decreasing reaction pressure. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2010
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