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Platinum(II)-mediated dehydrosulfurization and oxidative carbon-carbon coupling in the gas-phase decomposition of thioethers
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SYSNO ASEP 0326524 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Platinum(II)-mediated dehydrosulfurization and oxidative carbon-carbon coupling in the gas-phase decomposition of thioethers Author(s) Butschke, B. (DE)
Schlangen, M. (DE)
Schröder, Detlef (UOCHB-X)
Schwarz, H. (DE)Number of authors 4 Source Title International Journal of Mass Spectrometry. - : Elsevier - ISSN 1387-3806
Roč. 283, č. 1 (2009), s. 3-8Number of pages 6 s. Language eng - English Country NL - Netherlands Keywords bond activation ; bond formation ; platinum chemistry ; reaction mechanisms ; thio ethers Subject RIV CF - Physical ; Theoretical Chemistry CEZ AV0Z40550506 - UOCHB-X (2005-2011) UT WOS 000266808800003 DOI 10.1016/j.ijms.2008.10.019 Annotation The ion/molecule reaction of [Pt(bipy – H)]+ (bipy = 2,2'-bipyridine) with dimethyl sulfide leads to the loss of ethene in the main reaction channel. This process corresponds to a formal dehydrosulfurization (DHS) accompanied by oxidative C–C coupling. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434 Year of Publishing 2010
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