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Thermodynamic study of surfaces of liquid polybutadienes and their interfaces with poly(dimethylsiloxane)
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SYSNO ASEP 0325346 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Thermodynamic study of surfaces of liquid polybutadienes and their interfaces with poly(dimethylsiloxane) Title Thermodynamická studie povrchů kapalnách polybutadienů a jejich fázového rozhraní s poly(dimethylsiloxanem) Author(s) Jůza, Josef (UMCH-V) RID, ORCID Source Title Journal of Applied Polymer Science. - : Wiley - ISSN 0021-8995
Roč. 113, č. 1 (2009), s. 169-180Number of pages 12 s. Language eng - English Country US - United States Keywords polybutadiene ; Krasol TM ; liquid rubber Subject RIV CD - Macromolecular Chemistry R&D Projects IAC4050601 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000265904500020 DOI 10.1002/app.29678 Annotation Surface tension of liquid polybutadienes (PBD) as well as interfacial tension between them and poly(dimethylsiloxane) (PDMS) were measured in the temperature range from 25 to 150°C. The measured pressure–volume–temperature (PVT) data were used for the determination of reduction parameters of pressure, volume, and temperature in several equations of state for polymers. Interfacial tensions were used to determine Flory-Huggins interaction parameters. The estimate of the influence of PBD modifications on enthalpic and entropic component of interaction parameters was made. Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2010
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