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Thermodynamic study of surfaces of liquid polybutadienes and their interfaces with poly(dimethylsiloxane)

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    SYSNO ASEP0325346
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleThermodynamic study of surfaces of liquid polybutadienes and their interfaces with poly(dimethylsiloxane)
    TitleThermodynamická studie povrchů kapalnách polybutadienů a jejich fázového rozhraní s poly(dimethylsiloxanem)
    Author(s) Jůza, Josef (UMCH-V) RID, ORCID
    Source TitleJournal of Applied Polymer Science. - : Wiley - ISSN 0021-8995
    Roč. 113, č. 1 (2009), s. 169-180
    Number of pages12 s.
    Languageeng - English
    CountryUS - United States
    Keywordspolybutadiene ; Krasol TM ; liquid rubber
    Subject RIVCD - Macromolecular Chemistry
    R&D ProjectsIAC4050601 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    CEZAV0Z40500505 - UMCH-V (2005-2011)
    UT WOS000265904500020
    DOI10.1002/app.29678
    AnnotationSurface tension of liquid polybutadienes (PBD) as well as interfacial tension between them and poly(dimethylsiloxane) (PDMS) were measured in the temperature range from 25 to 150°C. The measured pressure–volume–temperature (PVT) data were used for the determination of reduction parameters of pressure, volume, and temperature in several equations of state for polymers. Interfacial tensions were used to determine Flory-Huggins interaction parameters. The estimate of the influence of PBD modifications on enthalpic and entropic component of interaction parameters was made.
    WorkplaceInstitute of Macromolecular Chemistry
    ContactEva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358
    Year of Publishing2010
Number of the records: 1  

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