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pH-Dependent Behavior of Hydrophobically Modified Polyelectrolyte Shells of Polymeric Nanoparticles
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SYSNO ASEP 0323590 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title pH-Dependent Behavior of Hydrophobically Modified Polyelectrolyte Shells of Polymeric Nanoparticles Title pH závislé chování hydrofobicky modifikovaných polyelektrolytových slupek polymerních nanočástic Author(s) Procházka, K. (CZ)
Matějíček, P. (CZ)
Uchman, M. (CZ)
Štěpánek, M. (CZ)
Humpolíčková, Jana (UFCH-W) RID
Hof, Martin (UFCH-W) RID, ORCID
Špírková, Milena (UMCH-V) RID, ORCIDSource Title Macromolecular Symposia. - : Wiley - ISSN 1022-1360
Roč. 273, - (2009), s. 95-102Number of pages 8 s. Language eng - English Country DE - Germany Keywords block polyelectrolyte micelles ; light scattering ; nonradiative excitation energy transfer ; time-resolved fluorescence Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects IAA400500505 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) GA203/08/0465 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40400503 - UFCH-W (2005-2011) AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000262306600014 DOI 10.1002/masy.200851313 Annotation The self-assembled core-shell nanoparticles based on fluorescently double-tagged high-molar-mass polystyrene-block-poly(methacrylic acid), PS-PMA, were prepared in aqueous buffers by dialysis from 1,4-dioxane - water mixtures. The conformations of shell-forming PMA chains were studied using nonradiative excitation energy transfer measurements. The study shows that two populations of distinctly different conformations (collapsed and stretched) coexist in the shell and their ratio depends on pH. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2009
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