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Synthesis and crystal structure of the singly tucked-in derivative of bis(phenyltetramethylcyclopentadienyl)titanium

SYSNO ASEP	0322859
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Synthesis and crystal structure of the singly tucked-in derivative of bis(phenyltetramethylcyclopentadienyl)titanium
Title	Příprava a krystalová struktura bis(fenyltetramethylcyklopentadienyl)titanového derivátu s jednou methylenovou vazbou
Author(s)	Pinkas, Jiří (UFCH-W)_{RID, ORCID} Císařová, I. (CZ) Conde, A. (ES) Fandos, R. (ES) Horáček, Michal (UFCH-W)_{RID, ORCID} Kubišta, Jiří (UFCH-W)_{RID, ORCID} Mach, Karel (UFCH-W)_{ORCID, RID}
Source Title	Inorganic Chemistry Communications. - : Elsevier - ISSN 1387-7003 Roč. 12, č. 1 (2009), s. 11-14
Number of pages	4 s.
Language	eng - English
Country	NL - Netherlands
Keywords	titanium ; titanocene ; tucked-in
Subject RIV	CF - Physical ; Theoretical Chemistry
R&D Projects	IAA400400708 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
	LC06071 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
CEZ	AV0Z40400503 - UFCH-W (2005-2011)
UT WOS	000262891400004
DOI	10.1016/j.inoche.2008.10.022
Annotation	Thermolysis of [TiMe2(eta(5)-C5Me4Ph)(2)] (4) at 145 degrees C for 5 h afforded the singly tucked-in paramagnetictitanocene [Ti(III)(eta(5)-C5Me4Ph){eta(5):eta(1)-C5Me3Ph(CH2)}] (9). In distinction to the singly tucked-in permethyltitanocene [Ti(III)(eta(5)-C5Me5)(eta(5):eta(1)-C5Me4(CH2))] (1) which was found crystallographically disordered [J.M. Fischer, W.E. Piers, V.G. Young, Jr., Organometallics 15 (1996) 2410] the single crystal X-ray diffraction analysis of 9 afforded molecular parameters with nearly by one order better precision as measured by esd-values.
Workplace	J. Heyrovsky Institute of Physical Chemistry
Contact	Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
Year of Publishing	2009

Number of the records: 1