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The collapse of hydrodynamic radii in pluronic PE6400 micelles in vicinity of supramolecular transition: dynamic light scattering, heat capacity and sound velocity measurements
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SYSNO ASEP 0322829 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title The collapse of hydrodynamic radii in pluronic PE6400 micelles in vicinity of supramolecular transition: dynamic light scattering, heat capacity and sound velocity measurements Title Kolapse hydrodynamického poloměru micel Pluroniku 6400 v okolí supramolekulárního přechodu: měření dynamického rozptylu světla, tepelné kapacity a rychlosti zvuku Author(s) Bakaeva, Z. (UZ)
Igamberdiev, K. (UZ)
Khabibulaev, P. (UZ)
Štěpánek, Petr (UMCH-V) RID, ORCID
Černoch, Peter (UMCH-V) RID, ORCIDNumber of authors 21 Source Title Nanostructured Materials for Advanced Technological Applications. - Dordrecht : Springer Netherlands, 2009 / Reithmaier J. P. ; Petkov P. ; Kulisch W. ; Popov C. - ISBN 978-1-4020-9915-1 Pages s. 137-142 Number of pages 6 s. Action Nanostructured Materials for Advanced Technological Applications Event date 01.06.2008-13.06.2008 VEvent location Sozopol Country BG - Bulgaria Event type WRD Language eng - English Country NL - Netherlands Keywords triblock copolymer ; supramolecular structures ; sound velocity ; heat capacity Subject RIV CD - Macromolecular Chemistry R&D Projects IAA4050403 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000264872500013 Annotation This work reports the results of a study of the microstructural and dynamical properties of self-assembled triblock copolymers. It was performed using adiabatic calorimetry, ultrasonic spectroscopy and dynamic light scattering. In the vicinity of supramolecular transitions, first aggregates occur; with further increasing temperature a spontaneous forming of compact structures was observed in the system. These results are supported by data of the shear viscosity and free internal volume parameters calculated in the framework of the Frenkel-Andrade approach. Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2009
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