Number of the records: 1

Synthesis, spectral, thermal and structural study of bis(2-bromobenzoato-O,O´)-bis(methyl-3-pyridylcarbamate-N)-zinc(II)

SYSNO ASEP	0320077
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Synthesis, spectral, thermal and structural study of bis(2-bromobenzoato-O,O´)-bis(methyl-3-pyridylcarbamate-N)-zinc(II)
Title	Syntéza, spektrální, termická a strukturní studie bis(2-brombenzoáto-O,O´)-bis(methyl-3-pyridylkarbamátu-N)-zinku(II)
Author(s)	Erdélyiová, A. (SK) Györyová, K. (SK) Gyepes, R. (CZ) Halás, L. (SK) Kovářová, Jana (UMCH-V)_RID
Source Title	Polyhedron. - : Elsevier - ISSN 0277-5387 Roč. 28, č. 1 (2009), s. 131-137
Number of pages	7 s.
Language	eng - English
Country	NL - Netherlands
Keywords	zinc ; methyl-3-pyridylcarbamate ; spectral, therma and structural study ; DFT calculation
Subject RIV	CD - Macromolecular Chemistry
CEZ	AV0Z40500505 - UMCH-V (2005-2011)
UT WOS	000262894800020
DOI	10.1016/j.poly.2008.09.017
Annotation	The present work describes the synthesis and characterization of [Zn(2-BrC6H4COO)2mpc2]. It was found out that the zinc atom is coordinated by two nitrogen atoms of two methyl-3-pyridylcarbamate ligands and is chelated by four oxygen atoms of two 2-bromobenzoates in a pseudo-octahedral geometry. The molecules are linked into a chain by hydrogen bridges between the NH group of methyl-3-pyridylcarbamate and one carboxylate oxygen atom from a neighbouring molecule. The complex proved to be thermally stable up to 165 °C.
Workplace	Institute of Macromolecular Chemistry
Contact	Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358
Year of Publishing	2009

Number of the records: 1