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Ag-ZSM-5 zeolite as high-temperature water-vapor sensor material

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    SYSNO ASEP0315575
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleAg-ZSM-5 zeolite as high-temperature water-vapor sensor material
    TitleZeolit Ag-ZSM-5 jako vysokoteplotní senzorový material pro detekci vodní páry
    Author(s) Sazama, Petr (UFCH-W) RID, ORCID
    Jirglová, Hana (UFCH-W) RID, ORCID
    Dědeček, Jiří (UFCH-W) RID, ORCID
    Source TitleMaterials Letters. - : ELSEVIER SCIENCE BV - ISSN 0167-577X
    Roč. 62, č. 27 (2008), s. 4239-4241
    Number of pages3 s.
    Languageeng - English
    CountryNL - Netherlands
    Keywordssenzors ; nanomaterials ; water-vapor sensing ; Ag clusters
    Subject RIVCF - Physical ; Theoretical Chemistry
    R&D ProjectsGA203/05/2309 GA ČR - Czech Science Foundation (CSF)
    CEZAV0Z40400503 - UFCH-W (2005-2011)
    UT WOS000259768600001
    DOI10.1016/j.matlet.2008.06.037
    AnnotationThe effect of the presence of water vapor in the gas stream on the absorption spectra of AgH-ZSM-5 zeolites at high temperatures was investigated using UV-Vis DR spectroscopy. Agmn+ silver species exhibiting an absorption band at 37 700 cm-1 are formed in highly loaded AgH-ZSM-5 treated in an oxygen stream. The presence of water in the gas stream results in the fast erosion of the band at 37 700 cm-1 and the intensity of the band is fully recovered under water-free conditions. Agmn+ silver species in the AgH-ZSM-5 zeolite and their optical properties are stable under high-temperature treatment of zeolite under various conditions. Thus, the preparation of chemically/thermally stable sensing material based on silicon-rich zeolites containing metal ion species suitable for sensor applications under sever conditions was demonstrated.
    WorkplaceJ. Heyrovsky Institute of Physical Chemistry
    ContactMichaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
    Year of Publishing2009
Number of the records: 1  

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