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Acidity of hydroxamic acids and amides

SYSNO ASEP	0194923
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Ostatní články
Title	Acidity of hydroxamic acids and amides
Author(s)	Böhm, S. (CZ) Exner, Otto (UOCHB-X)
Source Title	Organic & Biomolecular Chemistry. - : Royal Society of Chemistry - ISSN 1477-0520 Roč. 1, č. 7 (2003), s. 1176-1180
Number of pages	5 s.
Language	eng - English
Country	GB - United Kingdom
Keywords	hydroxamic acids ; DFT calculations ; isodesmic reactions
Subject RIV	CC - Organic Chemistry
R&D Projects	IAA4072005 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
CEZ	AV0Z4055905 - UOCHB-X
Annotation	Acidity of hydroxamic acids and amides was analyzed by means of isodesmic reactions. Energies were calculated at the B3LYP/AUG-cc-pVTZ/B3LYP/6-311+G(d,p) level. Both amides and hydroxamic acids are stabilized with respect to simpler reference molecules. However, their anions are stabilized still more and are responsible for the acidity.
Workplace	Institute of Organic Chemistry and Biochemistry
Contact	asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434
Year of Publishing	2004

Number of the records: 1