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Capillary zone electrophoresis in methanol: Migration behavior and background electrolytes
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SYSNO ASEP 0162506 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Ostatní články Title Capillary zone electrophoresis in methanol: Migration behavior and background electrolytes Author(s) Beckers, J. L. (NL)
Ackermans, M. T. (NL)
Boček, Petr (UIACH-O) RIDSource Title Electrophoresis. - : Wiley - ISSN 0173-0835
Roč. 24, č. 10 (2003), s. 1544-1552Number of pages 8 s. Language eng - English Country DE - Germany Keywords background electrolyte ; capillary zone electrophoresis ; migration behavior Subject RIV CB - Analytical Chemistry, Separation R&D Projects GA203/01/0401 GA ČR - Czech Science Foundation (CSF) GA203/02/0023 GA ČR - Czech Science Foundation (CSF) IAA4031103 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z4031919 - UIACH-O Annotation The concepts of pH* and pK* are considered for methanol as a solvent and pK* values are determined for several components in mixtures of water and methanol. The mathematical model developed for aqueous BGEs is applicable to BGEs in methanol, too, and the behavior of BGEs in methanol is comparable with that in water concerning the fronting or tailing character of peaks and the question of peaks and dips, although the mobilities and pK values can change significantly. Workplace Institute of Analytical Chemistry Contact Iveta Drobníková, drobnikova@iach.cz, Tel.: 532 290 234 Year of Publishing 2004
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