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Anionic polymerization of acrylates. Synthesis of (meth)acrylate di- and triblock copolymers using the Li ester-enolate/tert-alkoxide initiating system
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SYSNO ASEP 0105808 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Ostatní články Title Anionic polymerization of acrylates. Synthesis of (meth)acrylate di- and triblock copolymers using the Li ester-enolate/tert-alkoxide initiating system Title Aniontová polymerizace akrylátů. Syntéza (meth)akrylátových di- a triblokových kopolymerů iniciovaná systémem Li ester-enolát/tert-alkoxid Author(s) Vlček, Petr (UMCH-V) RID
Otoupalová, Jaroslava (UMCH-V)
Janata, Miroslav (UMCH-V) RID
Látalová, Petra (UMCH-V)
Kurková, Dana (UMCH-V)
Toman, Luděk (UMCH-V)
Masař, Bohumil (UMCH-V)Source Title Macromolecules. - : American Chemical Society - ISSN 0024-9297
Roč. 37, č. 2 (2004), s. 344-351Number of pages 8 s. Language eng - English Country US - United States Keywords ligated anionic polymerization ; block copolymers Subject RIV CD - Macromolecular Chemistry R&D Projects GA203/01/0513 GA ČR - Czech Science Foundation (CSF) KSK4050111 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z4050913 - UMCH-V Annotation Methacrylate di- and triblock copolymers composed of methyl (MMA), butyl (BuMA), 2-(dimethylamino)ethyl (DMAMA), and 2-ethylhexyl (EtHMA) methacrylates and tert-butyl acrylate (t-BuA) blocks were prepared by ligated anionic polymerization and characterized by SEC and NMR. A possible mechanism of self-termination and reactions of polymethacrylate chains bearing a few terminal acrylate units are briefly discussed. Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2005
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