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Interpolymer complexes based on the core/shell micelles. Interaction of polystyrene-block-poly(methacrylic acid) micelles with linear poly(2-vinylpyridine) in 1,4-dioxane water mixtures and in aqueous media
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SYSNO ASEP 0086428 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Ostatní články Title Interpolymer complexes based on the core/shell micelles. Interaction of polystyrene-block-poly(methacrylic acid) micelles with linear poly(2-vinylpyridine) in 1,4-dioxane water mixtures and in aqueous media Title Mezipolymerní komplexy založené na micelách jádro/slupka (core/shell). Interakce micel polystyren-block-poly(methakrylová kyselina) s lineárním poly(2-vinylpyridinem) ve směsi 1,4-dioxan/voda a ve vodném prostředí Author(s) Matějíček, P. (CZ)
Uchman, M. (CZ)
Lokajová, J. (CZ)
Štěpánek, M. (CZ)
Procházka, K. (CZ)
Špírková, Milena (UMCH-V) RID, ORCIDSource Title Journal of Physical Chemistry B. - : American Chemical Society - ISSN 1520-6106
Roč. 111, č. 29 (2007), s. 8394-8401Number of pages 8 s. Action International Symposium on Polyelectrolytes /6./ Event date 04.09.2006-08.09.2006 VEvent location Dresden Country DE - Germany Event type WRD Language eng - English Country US - United States Keywords polystyrene-block-poly(methacrylic acid) ; poly(2-vinylpyridine) ; core/shell micelles ; light scattering ; atomic force microscopy Subject RIV CD - Macromolecular Chemistry R&D Projects GA203/04/0490 GA ČR - Czech Science Foundation (CSF) IAA400500505 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40500505 - UMCH-V (2005-2011) DOI 10.1021/jp0685075 Annotation The size and structural changes of nanoparticles formed after the addition of poly(2-vinylpyridine), PVP, to block copolymer micelles of polystyrene-block-poly(methacrylic acid), PS-PMA, were studied by light scattering and atomic force microscopy. Due to the strong hydrogen bonding between PVP and PMA segments, complex structures based on the core/shell micelles form in mixed selective solvents. As proven by a combination of light scattering and atomic force microscopy, individual PS-PMA micelles are (glued) together by PVP chains. Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2008
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