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Interpolymer complexes based on the core/shell micelles. Interaction of polystyrene-block-poly(methacrylic acid) micelles with linear poly(2-vinylpyridine) in 1,4-dioxane water mixtures and in aqueous media

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    SYSNO ASEP0086428
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JOstatní články
    TitleInterpolymer complexes based on the core/shell micelles. Interaction of polystyrene-block-poly(methacrylic acid) micelles with linear poly(2-vinylpyridine) in 1,4-dioxane water mixtures and in aqueous media
    TitleMezipolymerní komplexy založené na micelách jádro/slupka (core/shell). Interakce micel polystyren-block-poly(methakrylová kyselina) s lineárním poly(2-vinylpyridinem) ve směsi 1,4-dioxan/voda a ve vodném prostředí
    Author(s) Matějíček, P. (CZ)
    Uchman, M. (CZ)
    Lokajová, J. (CZ)
    Štěpánek, M. (CZ)
    Procházka, K. (CZ)
    Špírková, Milena (UMCH-V) RID, ORCID
    Source TitleJournal of Physical Chemistry B. - : American Chemical Society - ISSN 1520-6106
    Roč. 111, č. 29 (2007), s. 8394-8401
    Number of pages8 s.
    ActionInternational Symposium on Polyelectrolytes /6./
    Event date04.09.2006-08.09.2006
    VEvent locationDresden
    CountryDE - Germany
    Event typeWRD
    Languageeng - English
    CountryUS - United States
    Keywordspolystyrene-block-poly(methacrylic acid) ; poly(2-vinylpyridine) ; core/shell micelles ; light scattering ; atomic force microscopy
    Subject RIVCD - Macromolecular Chemistry
    R&D ProjectsGA203/04/0490 GA ČR - Czech Science Foundation (CSF)
    IAA400500505 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    CEZAV0Z40500505 - UMCH-V (2005-2011)
    DOI10.1021/jp0685075
    AnnotationThe size and structural changes of nanoparticles formed after the addition of poly(2-vinylpyridine), PVP, to block copolymer micelles of polystyrene-block-poly(methacrylic acid), PS-PMA, were studied by light scattering and atomic force microscopy. Due to the strong hydrogen bonding between PVP and PMA segments, complex structures based on the core/shell micelles form in mixed selective solvents. As proven by a combination of light scattering and atomic force microscopy, individual PS-PMA micelles are (glued) together by PVP chains.
    WorkplaceInstitute of Macromolecular Chemistry
    ContactEva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358
    Year of Publishing2008
Number of the records: 1  

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