Number of the records: 1
Diphosphinoazine Rhodium(I) and Iridium(I) Complexes
- 1.
SYSNO ASEP 0049450 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Ostatní články Title Diphosphinoazine Rhodium(I) and Iridium(I) Complexes Title Difosfinoazinové komplexy rhodia(I) a iridia(I) Author(s) Pošta, Martin (UCHP-M)
Čermák, Jan (UCHP-M) RID, ORCID, SAI
Vojtíšek, P. (CZ)
Císařová, I. (CZ)Source Title Collection of Czechoslovak Chemical Communications. - : Ústav organické chemie a biochemie AV ČR, v. v. i. - ISSN 0010-0765
Roč. 71, č. 2 (2006), s. 197-206Number of pages 10 s. Language eng - English Country CZ - Czech Republic Keywords diphosphinoazines ; rhodium complexes ; iridium complexes Subject RIV CC - Organic Chemistry R&D Projects GA203/01/0554 GA ČR - Czech Science Foundation (CSF) GA203/99/M037 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40720504 - UCHP-M (2005-2011) Annotation The first rhodium complexes of diphosphinoazines [{RhCl(1,2-h:5,6-h- CH=CHCH2CH2CH=CHCH2CH2 )}2{m-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri) were prepared by cleavage of the bridge in chloro(cycloocta-1,5-diene)rhodium(I) dimer, the analogous iridium(I) complexes were also prepared for the first time. The X-ray structures of isostructural rhodium and iridium complexes with bis(dicyclohexylphosphino)pinacoloneazine were determined. Diphosphinoazine ligands in the complexes remained in (Z,Z) configuration bridging two RhCl(C8H12) units. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2007
Number of the records: 1