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Diphosphinoazine Rhodium(I) and Iridium(I) Complexes

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    SYSNO ASEP0049450
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JOstatní články
    TitleDiphosphinoazine Rhodium(I) and Iridium(I) Complexes
    TitleDifosfinoazinové komplexy rhodia(I) a iridia(I)
    Author(s) Pošta, Martin (UCHP-M)
    Čermák, Jan (UCHP-M) RID, SAI
    Vojtíšek, P. (CZ)
    Císařová, I. (CZ)
    Source TitleCollection of Czechoslovak Chemical Communications. - : Ústav organické chemie a biochemie AV ČR, v. v. i. - ISSN 0010-0765
    Roč. 71, č. 2 (2006), s. 197-206
    Number of pages10 s.
    Languageeng - English
    CountryCZ - Czech Republic
    Keywordsdiphosphinoazines ; rhodium complexes ; iridium complexes
    Subject RIVCC - Organic Chemistry
    R&D ProjectsGA203/01/0554 GA ČR - Czech Science Foundation (CSF)
    GA203/99/M037 GA ČR - Czech Science Foundation (CSF)
    CEZAV0Z40720504 - UCHP-M (2005-2011)
    AnnotationThe first rhodium complexes of diphosphinoazines [{RhCl(1,2-h:5,6-h- CH=CHCH2CH2CH=CHCH2CH2 )}2{m-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri) were prepared by cleavage of the bridge in chloro(cycloocta-1,5-diene)rhodium(I) dimer, the analogous iridium(I) complexes were also prepared for the first time. The X-ray structures of isostructural rhodium and iridium complexes with bis(dicyclohexylphosphino)pinacoloneazine were determined. Diphosphinoazine ligands in the complexes remained in (Z,Z) configuration bridging two RhCl(C8H12) units.
    WorkplaceInstitute of Chemical Process Fundamentals
    ContactEva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
    Year of Publishing2007
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