New chiral porphyrin-brucine gelator characterized by methods of circular dichroism
1.
SYSNO ASEP
0025788
Document Type
J - Journal Article
R&D Document Type
Journal Article
Subsidiary J
Ostatní články
Title
New chiral porphyrin-brucine gelator characterized by methods of circular dichroism
Title
Nové chirální porfyrin-brucinový gelátor charakterizovaný metodami cirkulárního dichroismu
Author(s)
Král, Vladimír (UOCHB-X) Pataridis, S. (CZ) Setnička, V. (CZ) Záruba, K. (CZ) Urbanová, M. (CZ) Volka, K. (CZ)
Source Title
Tetrahedron. - : Elsevier
- ISSN 0040-4020
Roč. 61, č. 23 (2005), s. 5499-5506
Number of pages
8 s.
Language
eng - English
Country
GB - United Kingdom
Keywords
porphyrinoids ; alkaloid ; brucine
Subject RIV
CC - Organic Chemistry
R&D Projects
GA303/05/0336 GA ČR - Czech Science Foundation (CSF)
CEZ
AV0Z40550506 - UOCHB-X (2005-2011)
Annotation
The first use of chiral alkaloid brucine to synthesize novel porphyrin-brucine conjugate capable of acting as a gelator of methanol and acetonitrile at extremely low level of concentration is reported. The synthesis, characterization and spectral properties of gelator based on a novel structural motif, quaternized alkaloid conjugates, are described.
