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Control of reactivity and regioselectivity for on-surface dehydrogenative aryl-aryl bond formation
- 1.0461488 - FZÚ 2017 RIV US eng J - Journal Article
Kocić, N. - Liu, X. - Chen, S. - Decurtins, S. - Krejčí, Ondřej - Jelínek, Pavel - Repp, J. - Liu, S.
Control of reactivity and regioselectivity for on-surface dehydrogenative aryl-aryl bond formation.
Journal of the American Chemical Society. Roč. 138, č. 17 (2016), s. 5585-5593. ISSN 0002-7863. E-ISSN 1520-5126
R&D Projects: GA ČR(CZ) GC14-16963J
Institutional support: RVO:68378271
Keywords : on-surface reaction * AFM * DFT * metal-organic coordination
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 13.858, year: 2016
Here we exploit a combined STM/AFM technique to demonstrate the on-surface formation of complex molecular architectures built up from a heteroaromatic precursor, the tetracyclic pyrazino[2,3-f][4,7]phenanthroline (pap) molecule. Selective intermolecular aryl–aryl coupling via dehydrogenative C–H activation occurs on Au(111) upon thermal annealing under ultrahigh vacuum (UHV) conditions.
Permanent Link: http://hdl.handle.net/11104/0261790
Number of the records: 1