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Electronic structure of Pu carbides: photoelectron spectroscopy

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    0313294 - FZÚ 2009 RIV NL eng J - Journal Article
    Gouder, T. - Havela, L. - Shick, Alexander - Huber, F.
    Electronic structure of Pu carbides: photoelectron spectroscopy.
    [Elektronová struktura v karbidech plutonia: fotoelektronová spektroskopie.]
    Physica B-Condensed Matter. Roč. 403, č. 5-9 (2008), s. 852-853. ISSN 0921-4526. E-ISSN 1873-2135
    R&D Projects: GA AV ČR(CZ) IAA100100530
    Grant - others:EU(XE) RITA-CT-2006-026176
    Institutional research plan: CEZ:AV0Z10100520
    Keywords : photoemission * electronic structure * plutonium
    Subject RIV: BM - Solid Matter Physics ; Magnetism
    Impact factor: 0.822, year: 2008

    Valence-band photoelectron spectra of Pu2C3 and PuC0.85 reveal the same type of 5f features below the Fermi level as observed for majority of other Pu systems. They appear at the same energies (0–0.1, 0.5, and 0.85 eV) and their intensity is higher for Pu2C3 than for PuC0.85. They can be attributed to the 5f5 final-state multiplet originating in the 5f6 component of the ground state. The higher 5f occupancy (5.48) calculated in Pu2C3, explains its non-magnetic character.

    Studium fotoelektronových spekter Pu2C3 a PuC odhalilo stejný typ funkcí 5f pod hladinou Fermi, jak bylo pozorováno u většiny ostatních systémů Pu.
    Permanent Link: http://hdl.handle.net/11104/0164160

     
     
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