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Structural, Redox and Spectrometric Characterization of Energetic Material FOX-7 (2,2-dinitroethene-1,1-diamine) in Solution
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SYSNO ASEP 0459781 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title Structural, Redox and Spectrometric Characterization of Energetic Material FOX-7 (2,2-dinitroethene-1,1-diamine) in Solution Author(s) Šimková, Ludmila (UFCH-W) RID, ORCID
Ludvík, Jiří (UFCH-W) RID, ORCIDSource Title XXXVI. Moderní elektrochemické metody. Sborník přednášek. - Ústí nad Labem : Best servis, 2016 / Navrátil T. ; Fojta M. ; Schwarzová K. - ISBN 978-80-905221-4-5 Pages s. 237-241 Number of pages 5 s. Publication form Print - P Action Moderní elektrochemické metody /36./ Event date 23.05.2016 - 27.05.2016 VEvent location Jetřichovice Country CZ - Czech Republic Event type WRD Language eng - English Country CZ - Czech Republic Keywords FOX-7 ; 2,2-dinitroethene-1,1-diamine ; structure Subject RIV CG - Electrochemistry R&D Projects GA13-21704S GA ČR - Czech Science Foundation (CSF) Institutional support UFCH-W - RVO:61388955 UT WOS 000389898200054 Annotation The investigation of energetic materials, especially organic nitro-amino-derivatives, always has attracted attention of physical chemists. However, published articles demonstrate lack of systematic study of molecules based on aliphatic backbones, rather than aromatic structures. This work represents the first systematic electrochemical and spectrometric characterization of 2,2-dinitroethene-1,1-diamine (FOX-7) in aqueous and aprotic solvent. Based on the results obtained from combination of electrochemistry with spectrometric methods, the actual structure of FOX-7 in various media was revealed, its reducibility described and radical intermediates as well as products were intercepted, isolated and characterized. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2017
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