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Observation of Binuclear Palladium Clusters Upon ESI-MS Monitoring of the Suzuki-Miyaura Cross-Coupling Catalyzed by a Dichloro-bis(aminophosphine) Complex of Palladium

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    0363614 - UOCHB-X 2012 RIV US eng J - Journal Article
    Agrawal, Divya - Schröder, Detlef - Frech, C. M.
    Observation of Binuclear Palladium Clusters Upon ESI-MS Monitoring of the Suzuki-Miyaura Cross-Coupling Catalyzed by a Dichloro-bis(aminophosphine) Complex of Palladium.
    Organometallics. Roč. 30, č. 13 (2011), s. 3579-3587. ISSN 0276-7333
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : catalysis * C-C coupling * electrospray ionization * palladium * Suzuki-Miyaura coupling
    Subject RIV: CF - Physical ; Theoretical Chemistry
    Impact factor: 3.963, year: 2011

    Electrospray ionization mass spectrometry is used for monitoring the Suzuki-Miyaura reaction between bromobenzene and arylboronic acids. The ESI-MS inter alia reveal the formation of a dinuclear Pd0/PdII cluster.
    Permanent Link: http://hdl.handle.net/11104/0199366