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Enhancing thermoelectric properties of ScN films through twin domains
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SYSNO ASEP 0604694 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Enhancing thermoelectric properties of ScN films through twin domains Author(s) More Chevalier, Joris (FZU-D) ORCID, RID
Wdowik, U. D. (CZ)
Martan, J. (CZ)
Baba, T. (JP)
Cichoň, Stanislav (FZU-D) RID, ORCID
Levinský, Petr (FZU-D) RID, ORCID
Legut, D. (CZ)
de Prado, Esther (FZU-D) ORCID, RID
Hruška, Petr (FZU-D) ORCID
Pokorný, Jan (FZU-D) RID, ORCID
Bulíř, Jiří (FZU-D) RID, ORCID, SAI
Beltrami, C. (CZ)
Mori, T. (JP)
Novotný, Michal (FZU-D) RID, ORCID, SAI
Gregora, Ivan (FZU-D) RID, ORCID
Fekete, Ladislav (FZU-D) RID, ORCID
Volfová, Lenka (FZU-D) ORCID
Lančok, Ján (FZU-D) RID, ORCIDNumber of authors 18 Article number 100674 Source Title Applied Surface Science Advances. - : Elsevier - ISSN 2666-5239
Roč. 25, Jan (2025)Number of pages 12 s. Language eng - English Country NL - Netherlands Keywords thermoelectricity ; scandium nitride ; thin films ; seebeck coefficient Subject RIV BM - Solid Matter Physics ; Magnetism OECD category Condensed matter physics (including formerly solid state physics, supercond.) R&D Projects EH22_008/0004596 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) GA23-07228S GA ČR - Czech Science Foundation (CSF) Research Infrastructure e-INFRA CZ II - 90254 - CESNET, zájmové sdružení právnických osob Method of publishing Open access Institutional support FZU-D - RVO:68378271 UT WOS 001395064000001 EID SCOPUS 85212853629 DOI https://doi.org/10.1016/j.apsadv.2024.100674 Annotation Tailoring thermoelectric properties of ScN-based materials is of vital importance for their application, particularly at high operating temperatures. Here, we report on the thermoelectric properties of the ScN layers deposited on MgO (001) substrates by the DC reactive magnetron sputtering. The microstructure of the produced thin films is examined by X-ray diffraction and atomic force microscopy, while their chemical composition and contamination by defects are determined by X-ray photoelectron spectroscopy. The effect of temperature on the phonon properties of ScN layers, having implications for their thermoelectric properties, is explored by Raman spectroscopy. The results of our experiments are confronted with those following from the first-principles studies. We find that the ScN/MgO(001) layers with twin-domain structure reveal enhanced thermoelectric properties at elevated temperature as compared to those measured for almost defect- and domain-free layers, namely, enlarged Seebeck coefficient by about 30% and over two and a half times increased figure of merit at 800 K. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2026 Electronic address https://hdl.handle.net/11104/0365804
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