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Electrochemistry and band structure of semiconductors (TiO2, SnO2, ZnO): Avoiding pitfalls and textbook errors
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SYSNO ASEP 0580509 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Electrochemistry and band structure of semiconductors (TiO2, SnO2, ZnO): Avoiding pitfalls and textbook errors Author(s) Kavan, Ladislav (UFCH-W) RID, ORCID Source Title Journal of Solid State Electrochemistry. - : Springer - ISSN 1432-8488
Roč. 28, JAN 2024 (2024), s. 829-845Number of pages 17 s. Language eng - English Country DE - Germany Keywords Titanium dioxide ; Tin dioxide ; Zinc oxide Subject RIV CG - Electrochemistry OECD category Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis) R&D Projects GA22-24138S GA ČR - Czech Science Foundation (CSF) Method of publishing Open access Institutional support UFCH-W - RVO:61388955 UT WOS 001136172900002 EID SCOPUS 85181520670 DOI https://doi.org/10.1007/s10008-023-05770-w Annotation This paper reviews selected problems, which appear in literature dealing with TiO2, SnO2, and ZnO. Some of them have more universal impact to semiconductor electrochemistry. The electronic band structure is a key for understanding fundamental properties and for rational design of applications, but the uncertainty of specific values determined experimentally or by theoretical calculations should not be ignored. The inappropriate use of Mott-Schottky plot for characterization of certain semiconductor electrodes is another source of problems. Some other technical and formal issues in research and development of semiconductors are discussed. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2025 Electronic address https://link.springer.com/article/10.1007/s10008-023-05770-w
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