Rhodium(II)-catalyzed transannulation approach to N-fluoroalkylated indoles

Number of the records: 1

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SYSNO ASEP	0576199
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Rhodium(II)-catalyzed transannulation approach to N-fluoroalkylated indoles
Author(s)	Bakhanovich, Olga (UOCHB-X)_{ORCID, RID} Klepetářová, Blanka (UOCHB-X)_{RID, ORCID} Beier, Petr (UOCHB-X)_{RID, ORCID}
Source Title	Organic & Biomolecular Chemistry. - : Royal Society of Chemistry - ISSN 1477-0520 Roč. 21, č. 39 (2023), s. 7924-7927
Number of pages	4 s.
Language	eng - English
Country	GB - United Kingdom
Keywords	azoles
OECD category	Organic chemistry
R&D Projects	GA23-04659S GA ČR - Czech Science Foundation (CSF)
Method of publishing	Open access
Institutional support	UOCHB-X - RVO:61388963
UT WOS	001070855800001
EID SCOPUS	85173976841
DOI	https://doi.org/10.1039/D3OB01415K
Annotation	Copper(i)-catalyzed cycloaddition of substituted cyclohexenyl acetylenes with azido(per)fluoroalkanes afforded 4-cyclohexenyl-substituted N-(per)fluoroalkylated 1,2,3-triazoles. Their rhodium(ii)-catalyzed transannulation led to fused N-(per)fluoroalkyl pyrroles and subsequent oxidation provided N-(per)fluoroalkyl indoles.
Workplace	Institute of Organic Chemistry and Biochemistry
Contact	asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Jana Procházková, Tel.: 220 183 418
Year of Publishing	2024
Electronic address	https://doi.org/10.1039/D3OB01415K

Number of the records: 1