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Homobimetallic Au(I)–Au(I) and heterotrimetallic Au(I)–Fe(II)–Au(I) complexes with dialkyldithiophosphates and phosphine ligands: structural characterization, DFT analysis, and tyrosinase inhibitory and biological effects
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SYSNO ASEP 0573645 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Homobimetallic Au(I)–Au(I) and heterotrimetallic Au(I)–Fe(II)–Au(I) complexes with dialkyldithiophosphates and phosphine ligands: structural characterization, DFT analysis, and tyrosinase inhibitory and biological effects Author(s) Neshat, A. (IR)
Mahdavi, A. (IR)
Yousefshahi, R.Y. (IR)
Cheraghi, M. (IR)
Mobarakeh, A.M. (IR)
Mohammadi, S. (IR)
Eigner, Václav (FZU-D) RID, ORCID
Kučeráková, Monika (FZU-D) RID, ORCID
Dušek, Michal (FZU-D) RID, ORCID, SAI
Kaboudin, B. (IR)Number of authors 10 Source Title ACS Omega. - : American Chemical Society - ISSN 2470-1343
Roč. 8, č. 23 (2023), s. 20423-20439Number of pages 17 s. Language eng - English Country US - United States Keywords gold ; ligands ; mathematical methods ; metals ; crystal structure ; X-ray diffraction Subject RIV BM - Solid Matter Physics ; Magnetism OECD category Condensed matter physics (including formerly solid state physics, supercond.) R&D Projects EF16_019/0000760 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) Method of publishing Open access Institutional support FZU-D - RVO:68378271 UT WOS 001010435500001 EID SCOPUS 85163352812 DOI 10.1021/acsomega.3c00645 Annotation The role of bridging and terminal ligand electronic and steric properties on the structure and antiproliferative activity of two-coordinated gold(I) complexes was investigated on seven novel binuclear and trinuclear gold(I) complexes. In 1−7, the gold(I) centers adopt a two-coordinated linear geometry and are structurally similar. However, their structural features and antiproliferative properties highly depend upon subtle ligand substituent changes. All complexes were validated by 1H, 13C{1H}, 31P NMR, and IR spectroscopy. The solid-state structures of 1, 2, 3, 6, and 7 were confirmed using single-crystal X-ray diffraction. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2024 Electronic address https://hdl.handle.net/11104/0344040
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