Number of the records: 1
Formation of dimethoxy bridged dinuclear iron(III) complex of pyridoxal Schiff base with iron-catalyzed oxidative C–N bond cleavage – Structure, magnetic properties, and DFT calculations
- 1.
SYSNO ASEP 0563757 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Formation of dimethoxy bridged dinuclear iron(III) complex of pyridoxal Schiff base with iron-catalyzed oxidative C–N bond cleavage – Structure, magnetic properties, and DFT calculations Author(s) Murašková, V. (CZ)
Eigner, Václav (FZU-D) RID, ORCID
Dušek, Michal (FZU-D) RID, ORCID, SAI
Poplštein, J. (CZ)
Šturala, J. (CZ)
Sedmidubský, D. (CZ)Number of authors 6 Article number 116156 Source Title Polyhedron. - : Elsevier - ISSN 0277-5387
Roč. 228, Dec (2022)Number of pages 14 s. Language eng - English Country GB - United Kingdom Keywords Iron(III) complex ; pyridoxal Schiff base ; methoxy bridged ; crystal structure ; magnetic properties ; DFT calculations Subject RIV BM - Solid Matter Physics ; Magnetism OECD category Condensed matter physics (including formerly solid state physics, supercond.) Research Infrastructure e-INFRA CZ - 90140 - CESNET, zájmové sdružení právnických osob
CzechNanoLab - 90110 - Vysoké učení technické v BrněMethod of publishing Limited access Institutional support FZU-D - RVO:68378271 UT WOS 000876863500003 EID SCOPUS 85140708352 DOI 10.1016/j.poly.2022.116156 Annotation Mononuclear Fe(III) complex [FeL(N3)]⋅CH3OH, where L2– is the dianion of an unsymmetrical propyl-ethyl pentadentate Schiff base ligand condensed from pyridoxal and N-(2-aminoethyl)propane-1,3-diamine, and dinuclear Fe(III) complex [{FeL'}2(μ-OCH3)2]⋅2.5CH3OH⋅H2O, where L'2– is the dianion of tetradentate Schiff base ligand based on pyridoxal and ethylenediamine, have been synthesized and characterized by elemental analysis, X-ray structural analysis, FT-IR and mass spectrometry. The experimental magnetic properties of the complexes were compared with the data obtained from the dens ity functional theory (DFT) calculations. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2023 Electronic address https://doi.org/10.1016/j.poly.2022.116156
Number of the records: 1