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Exploring the materials space in the smallest particle size range: from heterogeneous catalysis to electrocatalysis and photocatalysis
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SYSNO ASEP 0557496 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Exploring the materials space in the smallest particle size range: from heterogeneous catalysis to electrocatalysis and photocatalysis Author(s) Jašík, Juraj (UFCH-W) ORCID, RID
Fortunelli, A. (IT)
Vajda, Štefan (UFCH-W) RID, ORCIDSource Title Physical Chemistry Chemical Physics. - : Royal Society of Chemistry - ISSN 1463-9076
Roč. 24, č. 20 (2022), s. 12083-12115Number of pages 33 s. Language eng - English Country GB - United Kingdom Keywords ray-absorption spectroscopy ; supported gold clusters ; in-situ gisaxs ; operando x-ray ; co oxidation ; electronic-structure ; hydrogen evolution ; highly efficient ; metal-clusters ; oxide-film Subject RIV CF - Physical ; Theoretical Chemistry OECD category Physical chemistry Method of publishing Open access Institutional support UFCH-W - RVO:61388955 UT WOS 000789923300001 EID SCOPUS 85131325730 DOI 10.1039/d1cp05677h Annotation Ultrasmall clusters of subnanometer size can possess unique and even unexpected physical and chemical propensities which make them interesting in various fields of basic science and for potential applications, such as catalysis, photocatalysis, electrocatalysis, and optical and chemical sensors, just to name a few examples. These small particles often offer the tunability of their performance in an atom-by-atom fashion and an economic atom-efficient use of the metal loading. In this paper we review recent progress in the characterization and theory of well-defined subnanometer clusters in catalytic processes, and discuss their optical properties and stability, along with the potential of the size-selected clusters for the understanding of catalytic processes and for the development of new classes of catalysts. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2023 Electronic address http://hdl.handle.net/11104/0331455
Number of the records: 1