Synthesis and catalytic properties of new polymeric monometallic composites based on copolymers of polypropylene glycol maleate phthalate with acrylic acid

0551256 - ÚACH 2022 RIV CH eng J - Journal Article
Burkeev, M. Z. - Shibayeva, S. R. - Khamitova, T. O. - Plocek, Jiří - Tazhbayev, Y. M. - Davrenbekov, S. Z. - Nurmaganbetova, M. T. - Kazhmuratova, A. T. - Zhumagalieva, T. S. - Kezdikbayeva, A. T.
Synthesis and catalytic properties of new polymeric monometallic composites based on copolymers of polypropylene glycol maleate phthalate with acrylic acid.
Polymers. Roč. 13, č. 24 (2021), č. článku 4369. E-ISSN 2073-4360
Institutional support: RVO:61388980
Keywords : Copolymers of polypropylene glycol maleate phthalate with acrylic acid * Electrocatalytic hydrogenation * Metal–polymer composite * Pyridine
OECD category: Inorganic and nuclear chemistry
Impact factor: 4.967, year: 2021
Method of publishing: Open access

Metal–polymer composites based on copolymers of polypropylene glycol maleate phthalate with acrylic acid and metallic nickel and silver were synthesized for the first time. The objects obtained were characterized by infrared (IR) and Raman spectroscopies, thermogravimetry, a scanning electron microscope with energy dispersive spectroscopy, and atomic emission spectrometry. The catalytic activity of new metal–polymer composites that exhibited a rather high efficiency in the reactions of electrocatalytic hydrogenation of pyridine was studied. It is shown that nanoparticles of metals are evenly distributed in the volume of the polymer matrix, more than 80% of nanoparticles are in the range from 25 to 40 nm and have spherical and rhombic shapes. The reusability of the obtained composites is shown.
Permanent Link: http://hdl.handle.net/11104/0327555