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Simple Electrochemical Characterization of ortho-carborane and Some of its Exo-skeletal Derivatives

  1. 1.
    SYSNO ASEP0535986
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleSimple Electrochemical Characterization of ortho-carborane and Some of its Exo-skeletal Derivatives
    Author(s) Fojt, Lukáš (BFU-R) RID, ORCID
    Nekvinda, Jan (UACH-T) RID, SAI, ORCID
    El Anwar, Suzan (UACH-T) SAI, ORCID, RID
    Grüner, Bohumír (UACH-T) RID, SAI, ORCID
    Havran, Luděk (BFU-R) RID, ORCID
    Fojta, Miroslav (BFU-R) RID, ORCID
    Number of authors6
    Source TitleElectroanalysis. - : Wiley - ISSN 1040-0397
    Roč. 32, č. 8 (2020), s. 1859-1866
    Number of pages8 s.
    Publication formPrint - P
    Languageeng - English
    CountryDE - Germany
    Keywordselectrode ; electrochemistry ; carboranes ; molecular sensors and probes ; screen printed electrodes ; glassy carbon electrode
    Subject RIVCB - Analytical Chemistry, Separation
    OECD categoryAnalytical chemistry
    Subject RIV - cooperationInstitute of Inorganic Chemistry - Inorganic Chemistry
    R&D ProjectsGA19-04630S GA ČR - Czech Science Foundation (CSF)
    GA18-27648S GA ČR - Czech Science Foundation (CSF)
    Method of publishingLimited access
    Institutional supportBFU-R - RVO:68081707 ; UACH-T - RVO:61388980
    UT WOS000534084900001
    EID SCOPUS85085052361
    DOI10.1002/elan.202060038
    AnnotationElectrochemical behaviour of 12 icosahedral carboranes ortho-, meta- and para-carborane with different exo-skeletal substituents was investigated. The study was done using phosphate buffers, in some cases with 20 % and 30 % dimethyl sulfoxide (DMSO) addition to increase the solubility of studied compounds. Commercial glassy carbon electrode or home-made screen printed electrodes were used. Distinct electrochemical responses were observed only for the ortho-carborane and its exo-skeletal derivatives. The study of different exo-skeletal substituents on the electrochemical behaviour of the carboranes is crucial for the intended use of these compounds as electrochemical labels of biomolecules.
    WorkplaceInstitute of Biophysics
    ContactJana Poláková, polakova@ibp.cz, Tel.: 541 517 244
    Year of Publishing2021
    Electronic addresshttps://onlinelibrary.wiley.com/doi/full/10.1002/elan.202060038
Number of the records: 1  

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