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Reductive Alkylation of Amines with Carboxylic Ortho Esters
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SYSNO ASEP 0525489 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Reductive Alkylation of Amines with Carboxylic Ortho Esters Author(s) Kadyrov, Renat (UACH-T) SAI, ORCID
Moebus, K. (DE)Number of authors 2 Source Title Advanced Synthesis & Catalysis. - : Wiley - ISSN 1615-4150
Roč. 362, č. 16 (2020), s. 3352-3357Number of pages 6 s. Language eng - English Country DE - Germany Keywords Alkylation ; Amines ; Heterogeneous catalysis ; Hydrogenation ; Ortho esters Subject RIV CA - Inorganic Chemistry OECD category Inorganic and nuclear chemistry Method of publishing Open access with time embargo (30.06.2021) Institutional support UACH-T - RVO:61388980 UT WOS 000544202500001 EID SCOPUS 85087158976 DOI 10.1002/adsc.202000510 Annotation We have demonstrated for the first time that carboxylic ortho esters could be used as an alkylating agent in the reductive alkylation of amines. A variety of amines, including amino acid esters, were alkylated affording mono-alkylated products with high selectivity in practical to high yields using standard heterogeneous catalysts. By applying acyclic ortho esters alkylation was completed at room temperature. (Figure presented.). Workplace Institute of Inorganic Chemistry Contact Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Year of Publishing 2021 Electronic address http://hdl.handle.net/11104/0310678
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