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Core-Shell ZnO:Ga-SiO.sub.2./sub. nanocrystals: limiting particle agglomeration and increasing luminescence via surface defect passivation
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SYSNO ASEP 0517113 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Core-Shell ZnO:Ga-SiO2 nanocrystals: limiting particle agglomeration and increasing luminescence via surface defect passivation Author(s) Procházková, Lenka (FZU-D)
Vaněček, V. (CZ)
Čuba, V. (CZ)
Pjatkan, R. (CZ)
Martinez-Turtos, R. (IT)
Jakubec, Ivo (UACH-T) SAI, RID, ORCID
Buryi, Maksym (FZU-D) RID, ORCID
Omelkov, S. (EE)
Auffray, E. (CH)
Lecoq, P. (CH)
Mihóková, Eva (FZU-D) RID, ORCID, SAI
Nikl, Martin (FZU-D) RID, ORCID, SAINumber of authors 12 Source Title RSC Advances. - : Royal Society of Chemistry
Roč. 9, č. 50 (2019), s. 28946-28952Number of pages 7 s. Language eng - English Country GB - United Kingdom Keywords ZnO ; SiO2 ; nanoparticles ; luminescence Subject RIV BM - Solid Matter Physics ; Magnetism OECD category Condensed matter physics (including formerly solid state physics, supercond.) Subject RIV - cooperation Institute of Inorganic Chemistry - Inorganic Chemistry R&D Projects GA17-06479S GA ČR - Czech Science Foundation (CSF) EF16_019/0000760 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) Method of publishing Open access Institutional support FZU-D - RVO:68378271 ; UACH-T - RVO:61388980 UT WOS 000487104200006 EID SCOPUS 85072562581 DOI 10.1039/C9RA04421C Annotation Heat treatment is needed to increase the luminescence intensity of ZnO:Ga particles, but it comes at the cost of higher particle agglomeration. Higher agglomeration results in low transparency of scintillating powder when embedded in a matrix and constitutes one of the biggest disadvantages, besides low light yield and low stopping power, of ZnO:Ga powder. Limiting ZnO:Ga particle size is therefore a key step in order to prepare highly luminescent and transparent composites with prospects for optical applications. In this work, SiO2 coating was successfully used to improve luminescence intensity or limitation of crystallite size growth during further annealing. Furthermore, ZnO:Ga and ZnO:Ga-SiO2 core–shells were embedded in a polystyrene matrix. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2020 Electronic address http://hdl.handle.net/11104/0302400
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