0507874 - FZÚ 2020 RIV US eng J - Journal Article
Tulic, S. - Waitz, T. - Čaplovičová, M. - Habler, G. - Varga, Marián - Kotlár, M. - Vretenár, V. - Romanyuk, Olexandr - Kromka, Alexander - Rezek, Bohuslav - Skákalová, V.
Covalent diamond-graphite bonding: mechanism of catalytic transformation.
ACS Nano. Roč. 13, č. 4 (2019), s. 4621-4630. ISSN 1936-0851. E-ISSN 1936-086X
R&D Projects: GA ČR GF16-34856L
Institutional support: RVO:68378271
Keywords : diamond-to-graphite transformation * Ni-catalyzed graphitization * diamond-graphite covalent bonding * atomically resolved TEM * electrical conductance
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 14.588, year: 2019 ; AIS: 3.914, rok: 2019
Method of publishing: Open access
DOI: https://doi.org/10.1021/acsnano.9b00692

Aberration-corrected transmission electron microscopy of the atomic structure of diamond−graphite interface after Ni-induced catalytic transformation reveals graphitic planes bound covalently to the diamond in the upright orientation. The covalent attachment, together with a significant volume expansion of graphite transformed from diamond, gives rise to uniaxial stress that is released through plastic deformation. We propose a comprehensive model explaining the Ni-mediated transformation of diamond to graphite and covalent bonding at the interface as well as the mechanism of relaxation of uniaxial stress. We also explain the mechanism of electrical transport through the graphitized surface of diamond. The result may thus provide a foundation for the catalytically driven formation of graphene−diamond nanodevices.
Permanent Link: http://hdl.handle.net/11104/0298830