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Aluminum Wire Meshes Coated with Co-Mn-Al and Co Oxides as Catalysts for Deep Ethanol Oxidation.

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    SYSNO ASEP0486085
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleAluminum Wire Meshes Coated with Co-Mn-Al and Co Oxides as Catalysts for Deep Ethanol Oxidation.
    Author(s) Jirátová, Květa (UCHP-M) RID, ORCID, SAI
    Kovanda, F. (CZ)
    Balabánová, Jana (UCHP-M) RID, ORCID, SAI
    Kšírová, P. (CZ)
    Source TitleCatalysis Today. - : Elsevier - ISSN 0920-5861
    Roč. 304, SI (2018), s. 165-171
    Number of pages7 s.
    ActionCzech-Italian-Spanish Symposium in Catalysis /7./
    Event date13.06.2017 - 17.06.2017
    VEvent locationTřešť
    CountryCZ - Czech Republic
    Event typeEUR
    Languageeng - English
    CountryNL - Netherlands
    KeywordsGA17-08389S ; Co-Mn-Al mixed oxides ; aluminum mesh
    Subject RIVCI - Industrial Chemistry, Chemical Engineering
    OECD categoryChemical process engineering
    R&D ProjectsGA17-08389S GA ČR - Czech Science Foundation (CSF)
    Institutional supportUCHP-M - RVO:67985858
    UT WOS000425179000021
    EID SCOPUS85030482361
    DOI10.1016/j.cattod.2017.09.046
    AnnotationAluminum meshes with different wire diameter and open space area were anodized in H2SO4 solution and then treated under hydrothermal conditions in aqueous solution of Co and Mn nitrates. The layered double hydroxide precursors formed on the supports surface were transformed into Co-Mn-Al mixed oxides after heating. For comparison, aluminum mesh coated with Co3O4 oxide was also prepared. Activity of the catalysts depended on the amount of active components deposited on the mesh. Comparison of specific activities at the same space velocity demonstrated the size of mixed oxides particles as the important parameter for oxidation activity: decreasing in particle size led to increased catalysts efficiency. The Co3O4 oxide deposited from Co(OH)2 suspension provided more active catalyst than Co-Mn-Al mixed oxides obtained by long-term hydrothermal treatment of the anodized aluminum meshes followed by heating.
    WorkplaceInstitute of Chemical Process Fundamentals
    ContactEva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
    Year of Publishing2019
Number of the records: 1  

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