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Intermolecular Formation of Two C−C Bonds across Olefins Enabled by Boron-Based Relay Strategies
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SYSNO ASEP 0477877 Document Type J - Journal Article R&D Document Type The record was not marked in the RIV Subsidiary J Článek ve WOS Title Intermolecular Formation of Two C−C Bonds across Olefins Enabled by Boron-Based Relay Strategies Author(s) Hidasová, Denisa (UOCHB-X) ORCID
Jahn, Ullrich (UOCHB-X) ORCIDSource Title Angewandte Chemie - International Edition. - : Wiley - ISSN 1433-7851
Roč. 56, č. 33 (2017), s. 9656-9658Number of pages 3 s. Language eng - English Country DE - Germany Keywords 1,2-metalate rearrangement ; C−C bond formation ; radical reactions ; transition metal catalysis ; vinyl boronates Subject RIV CC - Organic Chemistry OECD category Organic chemistry Institutional support UOCHB-X - RVO:61388963 UT WOS 000406798700001 EID SCOPUS 85021776697 DOI 10.1002/anie.201705046 Annotation Smooth handoff in the relay: Vinyl boronates enable the direct addition of nucleophilic and electrophilic or nucleophilic and radical-generating carbon reagents across the double bond with retention of the valuable boronate group. The key to the success of this difficult twofold C−C bond-formation strategy is the initial relay of the nucleophilic addition to boron and the rearrangement of a 1,2-metalate rearrangement, shuttling it to the carbon atom. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Jana Procházková, Tel.: 220 183 418 Year of Publishing 2018
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