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Electrochemical Hydrogen Oxidation in Toluene/LiCB11Me12: H2 as a Surrogate for Lithium Metal?
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SYSNO ASEP 0468867 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Electrochemical Hydrogen Oxidation in Toluene/LiCB11Me12: H2 as a Surrogate for Lithium Metal? Author(s) Pospíšil, Lubomír (UFCH-W) RID, ORCID
Kaleta, Jiří (UOCHB-X) RID, ORCID
Michl, Josef (UOCHB-X) RID, ORCIDSource Title ChemElectroChem. - : Wiley - ISSN 2196-0216
Roč. 3, č. 2 (2016), s. 332-336Number of pages 5 s. Language eng - English Country DE - Germany Keywords electrochemistry ; hydrogen ; lithium Subject RIV CG - Electrochemistry Subject RIV - cooperation Institute of Organic Chemistry and Biochemistry - Physical ; Theoretical Chemistry R&D Projects GA13-19213S GA ČR - Czech Science Foundation (CSF) Institutional support UFCH-W - RVO:61388955 ; UOCHB-X - RVO:61388963 UT WOS 000371254600019 EID SCOPUS 84958769422 DOI https://doi.org/10.1002/celc.201500332 Annotation In toluene containing LiCB11(CH3)(12) as the supporting electrolyte, the oxidation potential of H-2 on a platinized Pt electrode is a strong function of the composition of a basic buffer, lithium 2,2,6,6-tetramethylpiperidinate / 2,2,6,6-tetramethylpiperidine, and can approach the onset of the reduction of Li+. This suggests that only a moderate voltage might be needed to use H-2 as a surrogate for Li and to take advantage of the specific chemical reactivity of the latter. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2017
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