0468867 - ÚFCH JH 2017 RIV DE eng J - Journal Article
Pospíšil, Lubomír - Kaleta, Jiří - Michl, Josef
Electrochemical Hydrogen Oxidation in Toluene/LiCB11Me12: H2 as a Surrogate for Lithium Metal?
ChemElectroChem. Roč. 3, č. 2 (2016), s. 332-336. ISSN 2196-0216. E-ISSN 2196-0216
R&D Projects: GA ČR GA13-19213S
Institutional support: RVO:61388955 ; RVO:61388963
Keywords : electrochemistry * hydrogen * lithium
Subject RIV: CG - Electrochemistry; CF - Physical ; Theoretical Chemistry (UOCHB-X)
Impact factor: 4.136, year: 2016 ; AIS: 0.997, rok: 2016
DOI: https://doi.org/10.1002/celc.201500332

In toluene containing LiCB11(CH3)(12) as the supporting electrolyte, the oxidation potential of H-2 on a platinized Pt electrode is a strong function of the composition of a basic buffer, lithium 2,2,6,6-tetramethylpiperidinate / 2,2,6,6-tetramethylpiperidine, and can approach the onset of the reduction of Li+. This suggests that only a moderate voltage might be needed to use H-2 as a surrogate for Li and to take advantage of the specific chemical reactivity of the latter.
Permanent Link: http://hdl.handle.net/11104/0266689