0439949 - ÚOCHB 2015 RIV CZ eng C - Conference Paper (international conference)
Jaklová Dytrtová, Jana - Jakl, M. - Schröder, Detlef
Ferrocene Oxidation; a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry.
Sborník přednášek. XXXI. Moderní elektrochemické metody. Ústí nad Labem: BEST servis, 2011 - (Navrátil, T.; Barek, J.), s. 69-73. ISBN 978-80-254-9634-3.
[Moderní elektrochemické metody /31./. Jetřichovice (CZ), 23.05.2011-27.05.2011]
R&D Projects: GA ČR GA203/08/1487
Institutional research plan: CEZ:AV0Z40550506
Keywords : ESI-MS * DPASV * CV * ferrocene * base electrolyte
Subject RIV: CG - Electrochemistry

The coupling of ESI-MS with two-electrodes flowing cell was provided and tested on ferrocene system. The oxidation potential of ferrocene was 430 mV in Pt/Ag electrode system. The bis-coordinated ferrocene complex with base electrolyte (NaClO4) was found using DPASV provided in different accumulation potentials and its analogy was also observed as protonated cation in mass spectra. The impact of inserted accumulation potential on mass spectra was also studied; the inserted potential changes the natural pattern of ferrocene.
Permanent Link: http://hdl.handle.net/11104/0243314