0437918 - ÚFCH JH 2015 RIV DE eng J - Journal Article
Ehret, F. - Bubrin, M. - Záliš, Stanislav - Kaim, W.
Non-innocent Redox Behavior of Amidinato Ligands: Spectroscopic Evidence for Amidinyl Complexes.
Zeitschrift für anorganische und allgemeine Chemie. Roč. 640, č. 14 (2014), s. 2781-2787. ISSN 0044-2313. E-ISSN 1521-3749
Grant - others:COST(XE) CM1202
Institutional support: RVO:61388955
Keywords : Amidinato ligands * Non-innocent ligands * Ruthenium
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 1.160, year: 2014 ; AIS: 0.211, rok: 2014
DOI: https://doi.org/10.1002/zaac.201400306

The compounds [Ru-II(bmaa(-))(bpy)(2)](PF6) [1(PF6)], [Ru-II(bmaa(-))(Cym)Cl] (2), and [Ru-II(bmaa(-))(Cym)(py)](PF6) [3(PF6)] [bmaa(-) = N,N-bis(4-methoxyphenyl)acetamidinato, bpy = 2,2'-bipyridine, Cym = p-cymene, py = pyridine] were studied spectroelectrochemically (EPR, UV/Vis) to reveal metal-centered oxidation for 1(+) but bmaa(-)-based oxidation to yield amidinyl ligands in 2(+) and 3(2+).
Permanent Link: http://hdl.handle.net/11104/0241454