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Electrochemical control of a non-covalent binding between ferrocene and beta-cyclodextrin
- 1.0435070 - ÚFCH JH 2015 RIV GB eng J - Journal Article
Kolivoška, Viliam - Mohos, M. - Pobelov, I. V. - Rohrbach, S. - Yoshida, K. - Hong, W. - Fu, Y. C. - Moreno-Garcia, P. - Mészáros, G. - Broekmann, P. - Hromadová, Magdaléna - Sokolová, Romana - Valášek, M. - Wandlowski, T.
Electrochemical control of a non-covalent binding between ferrocene and beta-cyclodextrin.
Chemical Communications. Roč. 50, č. 79 (2014), s. 11757-11759. ISSN 1359-7345. E-ISSN 1364-548X
R&D Projects: GA ČR(CZ) GA14-05180S
Institutional support: RVO:61388955
Keywords : electrochemistry * spectroscopy * beta-cyclodextrin
Subject RIV: CG - Electrochemistry
Impact factor: 6.834, year: 2014
The forces required for the detachment of ferrocene (Fc) from beta-cyclodextrin (beta CD) in a single host (beta CD)-guest (Fc) complex were investigated using force spectroscopy under electrochemical conditions. The redox state of the guest Fc moiety as well as the structure of the supporting matrix was found to decisively affect the nanomechanical properties of the complex.
Permanent Link: http://hdl.handle.net/11104/0238989
Number of the records: 1