Exploration of 9-bromo[7]Helicene Reactivity

0393374 - ÚCHP 2014 RIV GB eng J - Journal Article
Žádný, Jaroslav - Velíšek, Petr - Jakubec, Martin - Sýkora, Jan - Církva, Vladimír - Storch, Jan
Exploration of 9-bromo[7]Helicene Reactivity.
Tetrahedron. Roč. 69, č. 30 (2013), s. 6213-6218. ISSN 0040-4020. E-ISSN 1464-5416
R&D Projects: GA ČR GAP207/10/1124; GA TA ČR TA01010646; GA MPO FR-TI3/628
Institutional support: RVO:67985858
Keywords : helicene * palladium cross-coupling * microwave-assisted synthesis
Subject RIV: CC - Organic Chemistry
Impact factor: 2.817, year: 2013

Exploration of 9-bromo[7]helicene reactivity mainly in Pd-catalysed reactions is reported. Palladium catalysed carbon – carbon and carbon – heteroatom coupling reactions provide a large portfolio of racemic helicenes bearing different functional groups in good to excellent yields. Many of the reactions were performed in the microwave reactor keeping reaction time to a minimum compared with conventional synthetic methods.
Permanent Link: http://hdl.handle.net/11104/0222105