0383777 - ÚOCHB 2013 RIV DE eng J - Journal Article
Shaffer, Christopher - Schröder, Detlef - Gutz, Ch. - Lutzen, A.
Intramolecular C-H Bond Activation through a Flexible Ester Linkage.
Angewandte Chemie - International Edition. Roč. 51, č. 32 (2012), s. 8097-8100. ISSN 1433-7851. E-ISSN 1521-3773
Grant - others:European Research Council(XE) AdG HORIZOMS
Institutional support: RVO:61388963
Keywords : C-H activation * copper * gas phase * ion mobility * oxidation
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 13.734, year: 2012 ; AIS: 3.523, rok: 2012
DOI: https://doi.org/10.1002/anie.201203163

The selective functionalization of alkanes is a hallmark challenge within transition-metal catalysis. This important field continues to be advanced by fundamental investigations of ion/molecule reactions in the gas phase. Conceptually, diatomic metal-oxide ions (e.g., MgO+, VO+, FeO+, NiO+, and PtO+) have provided many of the most impressive results in this field and have even demonstrated remarkable reactivity with methane; recently, also the reactive CuO+ cation has been studied.
Permanent Link: http://hdl.handle.net/11104/0213615