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Biotransformation of (1S)-2-Carene and (1S)-3-Carene by Picea abies Suspension Culture
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SYSNO ASEP 0369831 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Biotransformation of (1S)-2-Carene and (1S)-3-Carene by Picea abies Suspension Culture Author(s) Dvořáková, Marcela (UEB-Q) RID, ORCID
Valterová, Irena (UOCHB-X) RID, ORCID
Šaman, David (UOCHB-X) RID, ORCID
Vaněk, Tomáš (UEB-Q) RID, ORCIDSource Title Molecules. - : MDPI
Roč. 16, č. 12 (2011), s. 10541-10555Number of pages 15 s. Language eng - English Country CH - Switzerland Keywords biotransformation ; carene ; oxidation Subject RIV ED - Physiology R&D Projects ME08070 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) 2B08058 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) CEZ AV0Z50380511 - UEB-Q (2005-2011) AV0Z40550506 - UOCHB-X (2005-2011) UT WOS 000298411200054 DOI 10.3390/molecules161210541 Annotation Biotransformation of (1S)-2-carene and (1S)-3-carene by Picea abies suspension culture led to the formation of oxygenated products. (1S)-2-Carene was transformed slowly and the final product was identified as (1S)-2-caren-4-one. On the other hand, the transformation of (1S)-3-carene was rapid and finally led to the formation of (1S)-3-caren-5-one and (1S)-2-caren-4-one as equally abundant major products. The time-course of the reaction indicates that some products abundant at the beginning of the reaction (e.g. (1S,3S,4R)-3,4-epoxycarane and (1R)-p-mentha-1(7),2-dien-8-ol) were consumed by a subsequent transformations. Thus, a precise selection of the biotransformation time may be used for a production of specific compounds. Workplace Institute of Experimental Botany Contact David Klier, knihovna@ueb.cas.cz, Tel.: 220 390 469 Year of Publishing 2012
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