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Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen
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SYSNO ASEP 0361469 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen Author(s) Beier, Petr (UOCHB-X) RID, ORCID
Pastýříková, Tereza (UOCHB-X) RIDNumber of authors 2 Source Title Tetrahedron Letters. - : Elsevier - ISSN 0040-4039
Roč. 52, č. 34 (2011), s. 4392-4394Number of pages 3 s. Language eng - English Country GB - United Kingdom Keywords pentafluorosulfanyl group ; vicarious nucleophilic substitution ; hydroxylation Subject RIV CC - Organic Chemistry R&D Projects GAP207/11/0344 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40550506 - UOCHB-X (2005-2011) UT WOS 000293987000007 DOI 10.1016/j.tetlet.2011.06.011 Annotation Para- and meta-nitro-(pentafluorosulfanyl)benzenes react with anions of cumyl hydroperoxide in the presence of t-BuOK in liquid ammonia to form nitro-(pentafluorosulfanyl)phenols. Their reduction with hydrogen in the presence of Raney-Nickel provides amino-(pentafluorosulfanyl)phenols. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Jana Procházková, Tel.: 220 183 418 Year of Publishing 2012
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